Chemistry - What is an exocyclic double bond?
Solution 1:
Surely you are aware that the calculation of this sort is but a very rough estimate, yet still I feel the urge to stress that once more. Having said that, let's look at the double bond in the first cycle: isn't it exocyclic with respect to the other cycle?
Solution 2:
The double bond B is exocyclic to ring 2 as it is attached to an atom which is shared between ring 1 and ring 2 while the double bond A is not connected to any ring 2 atoms and is within just one ring, hence making it endocyclic
for further references visit https://pharmaxchange.info/2012/08/ultraviolet-visible-uv-vis-spectroscopy-%E2%80%93-woodward-fieser-rules-to-calculate-wavelength-of-maximum-absorption-lambda-max-of-conjugated-dienes-and-polyenes/