What is the time complexity of javascript's array.indexOf?

The most efficient way to find the first index matching a value in an unsorted array is to just walk through the list in order, which is O(n). MDN also has some hints:

Returns the first index at which a given element can be found in the array, or -1 if it is not present.

[...]

fromIndex

Default: 0 (Entire array is searched)
The index to start the search at. If the index is greater than or equal to the array's length, -1 is returned, which means the array will not be searched. If the provided index value is a negative number, it is taken as the offset from the end of the array. Note: if the provided index is negative, the array is still searched from front to back. If the calculated index is less than 0, then the whole array will be searched.

In case you're wondering, here's how WebKit implements it:

EncodedJSValue JSC_HOST_CALL arrayProtoFuncIndexOf(ExecState* exec)
{
    // 15.4.4.14
    JSObject* thisObj = exec->hostThisValue().toThis(exec, StrictMode).toObject(exec);
    unsigned length = thisObj->get(exec, exec->propertyNames().length).toUInt32(exec);
    if (exec->hadException())
        return JSValue::encode(jsUndefined());

    unsigned index = argumentClampedIndexFromStartOrEnd(exec, 1, length);
    JSValue searchElement = exec->argument(0);
    for (; index < length; ++index) {
        JSValue e = getProperty(exec, thisObj, index);
        if (exec->hadException())
            return JSValue::encode(jsUndefined());
        if (!e)
            continue;
        if (JSValue::strictEqual(exec, searchElement, e))
            return JSValue::encode(jsNumber(index));
    }

    return JSValue::encode(jsNumber(-1));
}