Why does TimeSpan.ParseExact not work

Try this:

var t2 = TimeSpan.ParseExact(tmp, "c", System.Globalization.CultureInfo.InvariantCulture);

Source: Standard TimeSpan Format Strings

From the documentation:

Any other unescaped character in a format string, including a white-space character, is interpreted as a custom format specifier. In most cases, the presence of any other unescaped character results in a FormatException.

There are two ways to include a literal character in a format string:

• Enclose it in single quotation marks (the literal string delimiter).

• Precede it with a backslash ("\"), which is interpreted as an escape character. This means that, in C#, the format string must either be @-quoted, or the literal character must be preceded by an additional backslash.

The .NET Framework does not define a grammar for separators in time intervals. This means that the separators between days and hours, hours and minutes, minutes and seconds, and seconds and fractions of a second must all be treated as character literals in a format string.

So, the solution is to specify the format string as

TimeSpan.ParseExact(tmp, "hh\\:mm\\:ss", CultureInfo.InvariantCulture)