Xcode not stopping on breakpoint
I found the problem, Somehow the "Show Disassembly when debugging" was enabled in my Xcode which creates that problem. When I disabled it, all my debugger stopped in my source code.
You can find it under Product->Debug Workflow->Show Disassembly when debugging
Edit
In the latest Xcode it is under Debug->Debug Workflow->Show Disassembly when debugging
Xcode 6:
Go to Build Settings and make sure your "Strip style" is set up as "Non-Global Symbols" and not as "All Symbols"