Internal logic of the topos of simplicial sets
Short answer: the Kreisel-Putnam axiom $(\lnot p \to (q \lor r)) \to ((\lnot p \to q) \lor (\lnot p \to r))$ is not an intuitionistic tautology but it is valid for any subobjects of an object in the topos of simplicial sets.
The longer answer relies on an interesting characterization of the subobject classifier $\Omega$ of the topos of simplicial sets. (Thanks to Zhen Lin for helping me explain this characterization.) Sieves on $[n]$ in $\Delta$ can be identified with (possibly empty) abstract simplicial complexes $A$ with vertices drawn from $[n] = \{0,\ldots,n\}$. The sieve corresponding to $A$ consists of all order preserving maps $f:[m]\to[n]$ such that $\{f(0),\dots,f(m)\} \in A$. So, for each $n$, $\Omega(n)$ can be identified with the set of all such abstract simplicial complexes and for $g:[m]\to[n]$, $\Omega(g):\Omega(n)\to\Omega(m)$ takes each $A \in \Omega(n)$ to $B = \{x \subseteq [m] : \{g(i) \mid i \in x\} \in A\}$.
Interestingly, the lattice of abstract simplicial complexes on $[n]$ (with intersection and union) is the free distributive lattice $D_{n+1}$ on $n+1$ generators with a free top element (but no free bottom element though it still has a bottom element). Every finite bounded distributive lattice is a Heyting algebra by defining implication via $$(p \to q) \equiv \bigvee \{r \mid p \land r \leq q\},$$ where the big join makes sense since there are only finitely many possibilities for $r$. The logical operators $\land,\lor,\to:\Omega\times\Omega\to\Omega$ can be computed pointwise using the Heyting algebra structure of $D_{n+1}$. In other words, ${\land}(n):\Omega(n)\times\Omega(n)\to\Omega(n)$ takes each pair of abstract simplicial complexes $A_n,B_n$ on $[n]$ to $A_n \cap B_n$, and similarly for $\lor$ and $\to$. Thus any propositional formula which is true in $D_{n+1}$ for every $n$ will be valid for generalized truth values in the topos of simplicial sets. I don't know a simple characterization of this logic but it at least satisfies the Kreisel-Putnam axiom.
To verify the Kreisel-Putnam axiom in $D_{n+1}$, suppose $P$, $Q$, $R$ are abstract simplicial complexes over $[n]$. Note that $\lnot P$ consists of all nonempty $x \subseteq [n]$ that are disjoint from every element of $P$. If nonempty, which is the interesting case, this simplicial complex has a maximal element that I will denote $z$. Now $\lnot P \to (Q \lor R)$ consists of all $x \subseteq [n]$ such that $x \cap z \in Q \cup R$. Since $\lnot P \to Q$ (resp. $\lnot P \to R$) similarly consist of all $x \subseteq [n]$ such that $x \cap z \in Q$ (resp. $x \cap z \in R$), we see that $\lnot P \to (Q \lor R)$ and $(\lnot P \to Q) \lor (\lnot P \to R)$ correspond to the same abstract simplicial complexes.
I will augment François Dorais’s answer with an exact identification of the propositional logic.
Let $D_n$ be the free distributive lattice with a top, considered as a finite Heyting algebra. Algebras are a nuisance to work with, so let us compute the dual Kripke frame $F_n$, which validates the same formulas, but is much smaller and simpler. Since we are dealing with a finite algebra, the elements of $F_n$ are just the $\lor$-irreducible (which entails $\bot$-irreducible, i.e., nonzero) elements of $D_n$, ordered upside down.
If $\{x_i:i\in[n]\}$ is the set of free generators, each element of $D_n$ can be written in a disjunctive normal form $$a=\bigvee_{i\in I}\bigwedge_{j\in J_i}x_j,$$ where $J_i\subseteq[n]$, $I\ne\varnothing$, and $\{J_i:i\in I\}$ is an antichain. Clearly, if $a$ is $\lor$-irreducible, we must have $|I|=1$, thus $a$ is of the form $$a_J=\bigwedge_{j\in J}x_j$$ for some $J\subseteq[n]$. Moreover, we must have $J\ne[n]$ so that $a_J\ne\bot$. Conversely, it is not difficult to check that all $a_J$ with $J\ne[n]$ are indeed $\lor$-irreducible. Since $$a_J\le a_{J'}\iff J\supseteq J',$$ $F_n$ is just the powerset Boolean algebra without top: $$F_n\simeq\langle\mathcal P([n])\smallsetminus\{[n]\},{\subseteq}\rangle.$$ These Kripke frames are known as Medvedev frames, and the logic defined by $\{F_n:n\in\mathbb N\}$ is Medvedev’s logic (aka logic of finite problems), denoted LM or ML, based on Medvedev [1]. See e.g. Chagrov&Zakharyaschev [2,§2.9]. Thus, the logic of $\{D_n:n\in\mathbb N\}$ is also Medvedev’s logic.
Despite its seemingly simple definition, this logic is shrouded in mystery: it is particularly scandalous that half a century after its discovery, it is still an open problem if the logic is recursively axiomatizable. Let me just mention that apart from the Kreisel–Putnam axiom $$(\neg p\to q\lor r)\to(\neg p\to q)\lor(\neg p\to r),$$ Medvedev’s logic is also known to include Scott’s axiom $$((\neg\neg p\to p)\to p\lor\neg p)\to\neg\neg p\lor\neg p,$$ and an axiom identified by Andrews (reported in Gabbay [3]), which in fact implies both the Kreisel–Putnam and Scott axioms: $$((\neg p\to q)\to r\lor s)\to(p\to r)\lor(q\to s).$$ On the other hand, Medvedev’s logic is included in the logic of weak excluded middle $\mathrm{KC}=\mathrm{IPC}+(\neg p\lor\neg\neg p)$.
Medvedev’s logic has many interesting properties. In particular, it is the largest logic with the disjunction property that extends Kreisel–Putnam logic (Levin [4], Maksimova [5], cf. [2,Thm. 15.18]), and it is the only known superintuitionistic logic that simultaneously has the disjunction property and is structurally complete (Prucnal [6,7]).
References:
[1] Yuriĭ T. Medvedev: Finite problems. Doklady Akademii Nauk SSSR 142 (1962), no. 5, pp. 1015–1018, http://mi.mathnet.ru/eng/dan26117 (in Russian). English translation: Soviet Mathematics, Doklady 3 (1962), pp. 227–230.
[2] Alexander Chagrov and Michael Zakharyaschev: Modal logic. Oxford Logic Guides vol. 35, Oxford University Press, 1997.
[3] Dov Gabbay: Semantical investigations in Heyting’s intuitionistic logic. Synthese Library vol. 148, Springer, 1981, doi: 10.1007/978-94-017-2977-2.
[4] Leonid A. Levin: Some syntactic theorems on the calculus of finite problems of Yu. T. Medvedev. Doklady Akademii Nauk SSSR 185 (1969), no. 1, pp. 32–33, http://mi.mathnet.ru/eng/dan34473 (in Russian). English translation: Soviet Mathematics, Doklady 10 (1969), 288–290.
[5] Larisa L. Maksimova: On maximal intermediate logics with the disjunction property. Studia Logica 45 (1986), no. 1, pp. 69–75, doi: BF01881550.
[6] Tadeusz Prucnal: Structural completeness of Medvedev’s propositional calculus. Reports on Mathematical Logic 6 (1976), pp. 103–105.
[7] Tadeusz Prucnal: On two problems of Harvey Friedman. Studia Logica 38 (1979), no. 3, pp. 247–262, doi: 10.1007/BF00405383.
Francois's answer is exactly what I was looking for. I just want to record a different proof of the same fact, that the Kreisel-Putnam axiom $(\neg p \Rightarrow (q\vee r)) \Rightarrow ((\neg p \Rightarrow q) \vee (\neg p \Rightarrow r))$ holds in $\mathbf{sSet}$.
First note that for simplicial subsets $A,B\subseteq X$, the Heyting implication $(A\Rightarrow B)\subseteq X$ is (of course) the largest simplicial subset of $X$ whose intersection with $A$ is contained in $B$, and that this admits the following inductive description: an $n$-simplex of $X$ lies in $A\Rightarrow B$ iff (1) all of its faces lie in $(A\Rightarrow B)_{n-1}$ and (2) it is either in $B_n$ or not in $A_n$. (When $n=0$ the first condition is vacuous, so $(A\Rightarrow B)_0 = (X_0 \setminus A_0)\cup B_0$.)
In particular, $(\neg A)_n$ consists of the $n$-simplices of $X$ all of whose faces lie in $(\neg A)_{n-1}$ and which are not in $A_n$. But since $A$ is a simplicial subset, if $n>0$ the second condition is implied by the first: if all (indeed, any) of the faces of an $n$-simplex lie in $\neg A$, they do not lie in $A$, and so the $n$-simplex cannot be in $A$ either. Thus, $\neg A$ is the full simplicial subset on the vertices of $X$ not in $A$; "full" means that it contains a simplex as soon as it contains its vertices.
Now I claim that $(A\Rightarrow (Q\cup R)) = ((A\Rightarrow Q) \cup (A\rightarrow R))$ holds whenever $A$ is full (hence in particular when $A=\neg P$). It suffices to show the left-to-right containment. Since this is certainly true on 0-simplices, we inductively assume it true on $(n-1)$-simplices, and let $x\in (A\Rightarrow (Q\cup R)_n$. By assumption either $x\in Q_n$ or $x\in R_n$ or $x\notin A_n$. The first two cases are trivial, so suppose $x\notin A_n$.
Since $A$ is full, $x\notin A_n$ means that some vertex $v$ of $x$ is not in $A$. By induction, the unique $(n-1)$-dimensional face of $x$ not containing $v$, call it $y$, must be either in $A\Rightarrow Q$ or $A\Rightarrow R$; WLOG say it is in $A\Rightarrow Q$.
Now we can prove by induction on $k$ that every $k$-dimensional face of $x$ is also in $A\Rightarrow Q$. Any such face must either be a face of $y$, in which case it is in $A\Rightarrow Q$ since $y$ is, or else contain $v$. In the latter case, it cannot be in $A$ since $v$ is not in $A$, so it is in $A\Rightarrow Q$ as soon as all its faces are, and this follows by the inductive hypothesis. Therefore, every face of $x$ is in $A\Rightarrow Q$, hence so is $x$.