Is there a keybind to minimize all windows, without a toggle?

It can be found in System--->Preferences--->Keyboard shortcuts

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This person found a way to do what you are looking for: http://www.cs.bgu.ac.il/~gwiener/linux/minimizing-all-windows-in-gnome/

  1. First install devilspie

    sudo apt-get install devilspie
    
  2. Then create a file called minimize.ds in your home folder. In that file put the following:

    (begin
      (minimize)
      (quit))
    

    Test it out by running: devilspie minimize.ds

  3. If it works as it should then add a shortcut: System ➜ Preferences ➜ Keyboard Shortcuts.

    Click on the Add button and fill in the fields as shown below, replacing YOURUSERNAME with your actual username.

    And finally double-click where it says Disabled and press your shortcut keys.

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Ctrl+Alt+D? You can set it in Gnome System->Preferences