$ \mathbb{C} $ is not isomorphic to the endomorphism ring of its additive group
Method 1: $\operatorname{End}(M)$ is not an integral domain.
Method 2: Count idempotents. There are only 2 idempotent elements of $\mathbb{C}$, but lots in $\operatorname{End}(M)$, including for example real and imaginary projections along with the identity and zero maps.
Method 3: Cardinality. Assuming a Hamel basis for $\mathbb{C}$ as a $\mathbb{Q}$ vector space, there are $2^\mathfrak{c}$ $\mathbb{Q}$ vector vector space endomorphisms of $\mathbb{C}$, but only $\mathfrak{c}$ elements of $\mathbb{C}$.
The endomorphism ring of $M$ is its endomorphism group as a vector space over $\mathbb{Q}$ (since any additive function on $\mathbb{C}$ is in fact $\mathbb{Q}$-linear, and any $\mathbb{Q}$-linear map is necessarily additive).
How many endomorphisms does a vector space over $\mathbb{Q}$ of dimension $\kappa\geq\aleph_0$ have? Turns out it has $2^{\kappa}$ endomorphisms. Any endomorphism is completely determined by the image of a basis. Fix a basis $\beta$ for $\mathbf{V}$ over $\mathbb{Q}$, which is of cardinality $\kappa$.
Each endomorphism corresponds to a function $\beta\to\mathop{\oplus}\limits_{b\in\beta}\mathbb{Q} = \mathbb{Q}^{(\beta)}$. So the cardinality of the endomorphism ring is the cardinality of $(\mathbb{Q}^{(\beta)})^{\beta}$.
The cardinality of $\mathbb{Q}^{(\beta)}$ is $|\beta|=\kappa$, so the entire thing has cardinality $$|\mathrm{end}(M)| = \left|\mathbb{Q}^{(\beta)}\right|^{|\beta|} = \kappa^{\kappa} = 2^{\kappa}.$$ (For a proof that if $\kappa$ is infinite and $2\leq\lambda\leq 2^{\kappa}$, then $\lambda^{\kappa} = 2^{\kappa}{}{}$, see this previous answer).
In the case of $M$ and $\mathbb{C}$, since $M$ is of dimension $\mathfrak{c}=2^{\aleph_0}$ as a $\mathbb{Q}$-vector space, you have that $|\mathrm{End}(M)| = 2^{\mathfrak{c}}\gt \mathfrak{c}=|\mathbb{C}|$. So there aren't enough elements in $\mathbb{C}$ to give you all the endomorphisms.
(The elements of $\mathbb{C}$ correspond to the $\mathbb{C}$-linear maps, of course, by simple multiplication; but here you want a lot more maps).