Mouse hover change image position and size

Use transform: scale(x, y) to scale the object.
Use transform: translate(x, y) to move the object.
Those two properties can also be combined: transform: scale(x, y) translate(x, y).

Example:

.btn-social {
    width: 100px;
    position: relative;
    opacity: 0.5;
    transition: 0.3s ease;
    cursor: pointer;
}

.btn-social:hover {
    opacity: 1;

    /** default is 1, scale it to 1.5 */
    transform: scale(1.5, 1.5);

    /** translate 50px from left, and 40px from top */
    /** transform: translate(50px, 40px); */

    /** combine both scale and translate */
    /** transform: scale(1.5, 1.5) translate(50px, 40px); */
}
<img src="http://sstatic.net/stackexchange/img/logos/so/so-icon.png?v=c78bd457575a" class="btn-social" />
<img src="http://sstatic.net/stackexchange/img/logos/so/so-icon.png?v=c78bd457575a" class="btn-social" /><br />
<img src="http://sstatic.net/stackexchange/img/logos/so/so-icon.png?v=c78bd457575a" class="btn-social" />
<img src="http://sstatic.net/stackexchange/img/logos/so/so-icon.png?v=c78bd457575a" class="btn-social" />

Check this http://jsfiddle.net/tNLUx/11/

Removed position: relative; from css

#btnSocial{
    width:100px;
    opacity: 0.5;
    -webkit-opacity: 0.5;
    -moz-opacity: 0.5;
    transition: 0.5s ease;
    -webkit-transition: 0.5s ease;
    -moz-transition: 0.5s ease;

}

Tags:

Html

Css

Hover