Norm of a symmetric matrix equals spectral radius
The norm of a matrix is defined as \begin{equation} \|A\| = \sup_{\|u\| = 1} \|Au\| \end{equation} Taking the singular value decomposition of the matrix $A$, we have \begin{equation} A = VD W^T \end{equation} where $V$ and $W$ are orthonormal and $D$ is a diagonal matrix. Since $V$ and $W$ are orthonormal, we have $\|V\| = 1$ and $\|W\| = 1$. Then $\|Av\| = \|D v\|$ for any vector $v$. Then we can maximize the norm of $Av$ by maximizing the norm of $Dv$.
By the definition of singular value decomposition, $D$ will have the singular values of $A$ on its main diagonal and will have zeros everywhere else. Let $\lambda_1, \ldots, \lambda_n$ denote these diagonal entries so that
\begin{equation} D = \left(\begin{array}{cccc} \lambda_1 & 0 & \ldots & 0 \\ 0 & \lambda_2 & \ldots & 0 \\ \vdots & & \ddots & \vdots \\ 0 & 0 & \ldots & \lambda_n \end{array}\right) \end{equation}
Taking some $v = (v_1, v_2, \ldots, v_n)^T$, the product $Dv$ takes the form \begin{equation} Dv = \left(\begin{array}{c} \lambda_1v_1 \\ \vdots \\ \lambda_nv_n \end{array}\right) \end{equation} Maximizing the norm of this is the same as maximizing the norm squared. Then we are trying to maximize the sum \begin{equation} S = \sum_{i=1}^{n} \lambda_i^2v_i^2 \end{equation} under the constraint that $v$ is a unit vector (i.e., $\sum_i v_i^2 = 1$). The maximum is attained by finding the largest $\lambda_i^2$ and setting its corresponding $v_i$ to $1$ and then setting each other $v_j$ to $0$. Then the maximum of $S$ (which is the norm squared) is the square of the absolutely largest eigenvalue of $A$. Taking the square root, we get the absolutely largest eigenvalue of $A$.
But the key point is exactly that your matrix is diagonalizable more specially that you can find an orthonormal basis of eigenvector $e_i$ for which you have $A e_i=\lambda_i e_i$.
Then your write for $x=\sum x_ie_i$ and you have $Ax=\sum x_i\lambda_i e_i$ so that $\|Ax\|^2=\sum\lambda_i^2x_i^2$ now by definition of the norm of matrix it gives you $$\frac{\|Ax\|}{\|x\|}\leq|\lambda_{i_0}|$$ therefore $\|A\|\leq|\lambda_{i_0}|$ where $\lambda_{i_0}$ is the greatest eigenvalue . Finally the identity $\|Ae_{i_0}\|=\|\lambda_{i_0}e_i\|$ gives you the inequality $\|A\|\geq|\lambda_{i_0}|$.