'Operation is not valid due to the current state of the object' error during postback

Somebody posted quite a few form fields to your page. The new default max introduced by the recent security update is 1000.

Try adding the following setting in your web.config's <appsettings> block. in this block you are maximizing the MaxHttpCollection values this will override the defaults set by .net Framework. you can change the value accordingly as per your form needs

<appSettings>
    <add key="aspnet:MaxHttpCollectionKeys" value="2001" />
 </appSettings>

For more information please read this post. For more insight into the security patch by microsoft you can read this Knowledge base article

I didn't apply paging on my gridview and it extends to more than 600 records (with checkbox, buttons, etc.) and the value of 2001 didn't work. You may increase the value, say 10000 and test.

<appSettings>
<add key="aspnet:MaxHttpCollectionKeys" value="10000" />
</appSettings>

For ASP.NET 1.1, this is still due to someone posting more than 1000 form fields, but the setting must be changed in the registry rather than a config file. It should be added as a DWORD named MaxHttpCollectionKeys in the registry under

HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\ASP.NET\1.1.4322.0

for 32-bit editions of Windows, and

HKEY_LOCAL_MACHINE\SOFTWARE\Wow6432Node\Microsoft\ASP.NET\1.1.4322.0

for 64-bit editions of Windows.