PHP cURL custom headers

$subscription_key  ='';
    $host = '';    
    $request_headers = array(
                    "X-Mashape-Key:" . $subscription_key,
                    "X-Mashape-Host:" . $host
                );

    $ch = curl_init();
    curl_setopt($ch, CURLOPT_URL, $url);
    curl_setopt($ch, CURLOPT_RETURNTRANSFER, 1);
    curl_setopt($ch, CURLOPT_HTTPHEADER, $request_headers);

    $season_data = curl_exec($ch);

    if (curl_errno($ch)) {
        print "Error: " . curl_error($ch);
        exit();
    }

    // Show me the result
    curl_close($ch);
    $json= json_decode($season_data, true);

curl_setopt($ch, CURLOPT_HTTPHEADER, array(
    'X-Apple-Tz: 0',
    'X-Apple-Store-Front: 143444,12'
));

http://www.php.net/manual/en/function.curl-setopt.php

Use the following Syntax

$ch = curl_init();
curl_setopt($ch, CURLOPT_URL,"http://www.example.com/process.php");
curl_setopt($ch, CURLOPT_POST, 1);
curl_setopt($ch, CURLOPT_POSTFIELDS,$vars);  //Post Fields
curl_setopt($ch, CURLOPT_RETURNTRANSFER, true);

$headers = [
    'X-Apple-Tz: 0',
    'X-Apple-Store-Front: 143444,12',
    'Accept: text/html,application/xhtml+xml,application/xml;q=0.9,*/*;q=0.8',
    'Accept-Encoding: gzip, deflate',
    'Accept-Language: en-US,en;q=0.5',
    'Cache-Control: no-cache',
    'Content-Type: application/x-www-form-urlencoded; charset=utf-8',
    'Host: www.example.com',
    'Referer: http://www.example.com/index.php', //Your referrer address
    'User-Agent: Mozilla/5.0 (X11; Ubuntu; Linux i686; rv:28.0) Gecko/20100101 Firefox/28.0',
    'X-MicrosoftAjax: Delta=true'
];

curl_setopt($ch, CURLOPT_HTTPHEADER, $headers);

$server_output = curl_exec ($ch);

curl_close ($ch);

print  $server_output ;