woocommerce_default_catalog_orderby options code example
Example: woocommerce_default_catalog_orderby desc
/**
* This code should be added to functions.php of your theme
**/
add_filter('woocommerce_default_catalog_orderby', 'custom_default_catalog_orderby');
function custom_default_catalog_orderby() {
return 'date'; // Can also use title and price
}