postgresql - add boolean column to table set default

ALTER TABLE users
  ADD COLUMN "priv_user" BOOLEAN DEFAULT FALSE;

you can also directly specify NOT NULL

ALTER TABLE users
  ADD COLUMN "priv_user" BOOLEAN NOT NULL DEFAULT FALSE;

UPDATE: following is only true for versions before postgresql 11.

As Craig mentioned on filled tables it is more efficient to split it into steps:

ALTER TABLE users ADD COLUMN priv_user BOOLEAN;
UPDATE users SET priv_user = 'f';
ALTER TABLE users ALTER COLUMN priv_user SET NOT NULL;
ALTER TABLE users ALTER COLUMN priv_user SET DEFAULT FALSE;

If you want an actual boolean column:

ALTER TABLE users ADD "priv_user" boolean DEFAULT false;