python pandas dataframe columns convert to dict key and value

If you want a simple way to preserve duplicates, you could use groupby:

>>> ptest = pd.DataFrame([['a',1],['a',2],['b',3]], columns=['id', 'value']) 
>>> ptest
  id  value
0  a      1
1  a      2
2  b      3
>>> {k: g["value"].tolist() for k,g in ptest.groupby("id")}
{'a': [1, 2], 'b': [3]}

See the docs for to_dict. You can use it like this:

df.set_index('id').to_dict()

And if you have only one column, to avoid the column name is also a level in the dict (actually, in this case you use the Series.to_dict()):

df.set_index('id')['value'].to_dict()

mydict = dict(zip(df.id, df.value))

If lakes is your DataFrame, you can do something like

area_dict = dict(zip(lakes.id, lakes.value))