Reading PSD file format
The ImageMagick libraries (which provide bindings for C#) also support the PSD format. They might be easier to get started with than getting into the Paint.NET code and also come with a quite free (BSD-like) license.
A simple sample (found at http://midimick.com/magicknet/magickDoc.html) using MagickNet would look like this:
using System;
static void Main(string[] args)
{
MagickNet.Magick.Init();
MagicNet.Image img = new MagicNet.Image("file.psd");
img.Resize(System.Drawing.Size(100,100));
img.Write("newFile.png");
MagickNet.Magick.Term();
}
Note: MagickNet has moved to http://www.codeproject.com/KB/dotnet/ImageMagick_in_VBNET.aspx
This guy do it easier:
http://www.codeproject.com/KB/graphics/simplepsd.aspx
With a C# library and a sample project.
I've tried with PS2 files and works ok.
Well, there's a PSD plugin for Paint.NET which I think is Open-Source which you might want to take a look at for starters:
http://frankblumenberg.de/doku/doku.php?id=paintnet:psdplugin#download
I have written a PSD parser which extracts raster format layers from all versions of PSD and PSB. http://www.telegraphics.com.au/svn/psdparse/trunk