Slash and backslash in sed
Use single quotes for the expression you used:
sed 's/\//\\\//g'
In double quotes, \
has a special meaning, so you have to backslash it:
sed "s/\//\\\\\//g"
But it's cleaner to change the delimiter:
sed 's=/=\\/=g'
sed "s=/=\\\/=g"
Try:
sed 's/\//\\\//g'
or using another delimiter to prevent you from escaping slash:
sed 's,/,\\/,g'