SQL Server 100% CPU Utilization - One database shows high CPU usage than others

You can see some reports in SSMS:

Right-click the instance name / reports / standard / top sessions

You can see top CPU consuming sessions. This may shed some light on what SQL processes are using resources. There are a few other CPU related reports if you look around. I was going to point to some more DMVs but if you've looked into that already I'll skip it.

You can use sp_BlitzCache to find the top CPU consuming queries. You can also sort by IO and other things as well. This is using DMV info which accumulates between restarts.

This article looks promising.

Some stackoverflow goodness from Mr. Ozar.

edit: A little more advice... A query running for 'only' 5 seconds can be a problem. It could be using all your cores and really running 8 cores times 5 seconds - 40 seconds of 'virtual' time. I like to use some DMVs to see how many executions have happened for that code to see what that 5 seconds adds up to.