Store Dictionary<string,string> in application settings

You can use this class derived from StringDictionary. To be useful for application settings it implements IXmlSerializable. Or you can use similar approach to implement your own XmlSerializable class.

public class SerializableStringDictionary : System.Collections.Specialized.StringDictionary, System.Xml.Serialization.IXmlSerializable
{
    public System.Xml.Schema.XmlSchema GetSchema()
    {
        return null;
    }

    public void ReadXml(System.Xml.XmlReader reader)
    {
        while (reader.Read() &&
            !(reader.NodeType == System.Xml.XmlNodeType.EndElement && reader.LocalName == this.GetType().Name))
        {
            var name = reader["Name"];
            if (name == null)
                throw new FormatException();

            var value = reader["Value"];
            this[name] = value;
        }
    }

    public void WriteXml(System.Xml.XmlWriter writer)
    {
        foreach (System.Collections.DictionaryEntry entry in this)
        {
            writer.WriteStartElement("Pair");
            writer.WriteAttributeString("Name", (string)entry.Key);
            writer.WriteAttributeString("Value", (string)entry.Value);
            writer.WriteEndElement();
        }
    }
}

Resulting XML fragment will look similar to:

...
<setting name="PluginSettings" serializeAs="Xml">
    <value>
        <SerializableStringDictionary>
            <Pair Name="property1" Value="True" />
            <Pair Name="property2" Value="05/01/2011 0:00:00" />
        </SerializableStringDictionary>
    </value>
</setting>
...

The simplest answer would be to use a row & column delimiter to convert your dictionary to a single string. Then you just need to store 1 string in the settings file.

If you don't need to use the settings designer or edit your settings with a text editor, you can create a simple class that derives from ApplicationSettingsBase:

namespace MyNamespace
{
    using System.Collections.Generic;
    using System.Configuration;

    /// <summary>
    /// Persistent store for my parameters.
    /// </summary>
    public class MySettings : ApplicationSettingsBase
    {
        /// <summary>
        /// The instance lock.
        /// </summary>
        private static readonly object InstanceLock = new object();

        /// <summary>
        /// The instance.
        /// </summary>
        private static MySettings instance;

        /// <summary>
        /// Prevents a default instance of the <see cref="MySettings"/> class 
        /// from being created.
        /// </summary>
        private MySettings()
        {
            // don't need to do anything
        }

        /// <summary>
        /// Gets the singleton.
        /// </summary>
        public static MySettings Instance
        {
            get
            {
                lock (InstanceLock)
                {
                    if (instance == null)
                    {
                        instance = new MySettings();
                    }
                }

                return instance;
            }
        }

        /// <summary>
        /// Gets or sets the parameters.
        /// </summary>
        [UserScopedSetting]
        [SettingsSerializeAs(SettingsSerializeAs.Binary)]
        public Dictionary<string, string> Parameters
        {
            get
            {
                return (Dictionary<string, string>)this["Parameters"];
            }

            set
            {
                this["Parameters"] = value;
            }
        }
    }
}

The real trick is the [SettingsSerializeAs(SettingsSerializeAs.Binary)] attribute. Most (all?) classes can get serialized this way where SettingsSerializeAs.String or SettingsSerializeAs.Xml wont work for a Dictionary.

Use this in your code as you would normal settings:

// this code untested...
MySettings.Instance.Parameters["foo"] = "bar";
MySettings.Instance.Parameters.Save();
MySettings.Instance.Parameters.Reload();
string bar;
if (!MySettings.Instance.Parameters.TryGetValue("foo", out bar))
{
    throw new Exception("Foobar");
}

If you want the Dictionary to serialize into something user editable, you must derive from Dictionary and play with TypeConverter (see Using Custom Classes with Application Settings).