Unity Project doesn't have solution file
If "Open C# Project" doesnt create the .sln file, try updating your external tools first.
In Unity, go to Edit > Preferences, and make sure that Visual Studio is selected as your preferred external editor.
This created the sln file for me.
I finally found the answer.
I closed Xamarin and inside Unity went Assets > Sync MonoDevelop Project Doing this created the two .sln projects: -csharp.sln and .sln