Using pair as key in a map (C++ / STL)

This is a similar version of what you want to do, just change the data types, that's all. Also, use a c++ string, not the one we use in c.

#include<bits/stdc++.h>
using namespace std;
#define  ll long long int
typedef pair<ll,ll> my_key_type;
typedef map<my_key_type,ll> my_map_type;
int  main()
{
    my_map_type m;
    m.insert(make_pair(my_key_type(30,40),6));
}   

Here's a working rewrite of the code in question:

#include <map>
#include <string>

class Key
{
  public: 
    Key(std::string s, int i)
    {
      this->s = s;
      this->i = i;
    }
    std::string s;
    int i;
    bool operator<(const Key& k) const
    {
      int s_cmp = this->s.compare(k.s);
      if(s_cmp == 0)
      {
        return this->i < k.i;
      }
      return s_cmp < 0;
    }
};

int main()
{


  Key p1 ("Apple", 45);
  Key p2 ("Berry", 20);

  std::map<Key,std::string> mapa;

  mapa[p1] = "Manzana";
  mapa[p2] = "Arandano";

  printf("mapa[%s,%d] --> %s\n",
    p1.s.c_str(),p1.i,mapa.begin()->second.c_str());
  printf("mapa[%s,%d] --> %s\n",
    p2.s.c_str(),p2.i,(++mapa.begin())->second.c_str());

  return 0;
}

std::map::insert takes a single argument: the key-value pair, so you would need to use:

mapa.insert(std::make_pair(p1, "Manzana"));

You should use std::string instead of C strings in your types. As it is now, you will likely not get the results you expect because looking up values in the map will be done by comparing pointers, not by comparing strings.

If you really want to use C strings (which, again, you shouldn't), then you need to use const char* instead of char* in your types.

And in general How can I use any kind of structure (objects, structs, etc) as a key in a map?

You need to overload operator< for the key type or use a custom comparator.

Alternatively to what James McNellis stated:

mapa.insert(std::make_pair(p1, "Manzana"));

you could use mapa.insert({p1, "Manzana"});