What are the Frobenius groups of order $100$?

I agree with your calculation. A routine search through the small groups library shows that only the groups $\mathtt{SmallGroup}(100,i)$ for $i=3,11,12$ are Frobenius groups.

Or you could prove it theoretically. It is easy to see that the only possible order of a Frobenius kernel $K$ in such a group is $25$. A Frobenius complement must be cyclic of order $4$ and act fixed point freely by conjugation on $K$.

If $K$ is cyclic then ${\rm Aut}(K)$ is cyclic and there is only one possible action.

Otherwise $K$ is elementary abelian and ${\rm Aut}(K) \cong {\rm GL}(2,5)$. Elements of order $4$ are diagonalizable, and there are two two conjugacy classes of subgroups of order $4$ with fixed point free action, with representatives $\left\langle \left(\begin{array}{cc}2&0\\0&2\end{array} \right)\right\rangle$ and $\left\langle \left(\begin{array}{cc}2&0\\0&3\end{array} \right)\right\rangle.$