What does the "@" symbol mean in reference to lists in Haskell?

The @ Symbol is used to both give a name to a parameter and match that parameter against a pattern that follows the @. It's not specific to lists and can also be used with other data structures.

This is useful if you want to "decompose" a parameter into it's parts while still needing the parameter as a whole somewhere in your function. One example where this is the case is the tails function from the standard library:

tails                   :: [a] -> [[a]]
tails []                =  [[]]
tails xxs@(_:xs)        =  xxs : tails xs

Yes, it's just syntactic sugar, with @ read aloud as "as". ps@(p:pt) gives you names for

1. the list: ps
2. the list's head : p
3. the list's tail: pt

Without the @, you'd have to choose between (1) or (2):(3).

This syntax actually works for any constructor; if you have data Tree a = Tree a [Tree a], then t@(Tree _ kids) gives you access to both the tree and its children.