What is the electric field in a parallel plate capacitor?
When discussing an ideal parallel-plate capacitor, $\sigma$ usually denotes the area charge density of the plate as a whole - that is, the total charge on the plate divided by the area of the plate. There is not one $\sigma$ for the inside surface and a separate $\sigma$ for the outside surface. Or rather, there is, but the $\sigma$ used in textbooks takes into account all the charge on both these surfaces, so it is the sum of the two charge densities.
$$\sigma = \frac{Q}{A} = \sigma_\text{inside} + \sigma_\text{outside}$$
With this definition, the equation we get from Gauss's law is
$$E_\text{inside} + E_\text{outside} = \frac{\sigma}{\epsilon_0}$$
where "inside" and "outside" designate the regions on opposite sides of the plate. For an isolated plate, $E_\text{inside} = E_\text{outside}$ and thus the electric field is everywhere $\frac{\sigma}{2\epsilon_0}$.
Now, if another, oppositely charge plate is brought nearby to form a parallel plate capacitor, the electric field in the outside region (A in the images below) will fall to essentially zero, and that means
$$E_\text{inside} = \frac{\sigma}{\epsilon_0}$$
There are two ways to explain this:
The simple explanation is that in the outside region, the electric fields from the two plates cancel out. This explanation, which is often presented in introductory textbooks, assumes that the internal structure of the plates can be ignored (i.e. infinitely thin plates) and exploits the principle of superposition.
The more realistic explanation is that essentially all of the charge on each plate migrates to the inside surface. This charge, of area density $\sigma$, is producing an electric field in only one direction, which will accordingly have strength $\frac{\sigma}{\epsilon_0}$. But when using this explanation, you do not also superpose the electric field produced by charge on the inside surface of the other plate. Those other charges are the terminators for the same electric field lines produced by the charges on this plate; they're not producing a separate contribution to the electric field of their own.
Either way, it's not true that $\lim_{d\to 0} E = \frac{2\sigma}{\epsilon_0}$.