What is the HTML5 equivalent to the align attribute in table cells?

You can use inline css :
<td style = "text-align: center;">

If they're block level elements they won't be affected by text-align: center;. Someone may have set img { display: block; } and that's throwing it out of whack. You can try:

td { text-align: center; }
td * { display: inline; }

and if it looks as desired you should definitely replace * with the desired elements like:

td img, td foo { display: inline; }