What's the best/easiest GUI Library for Ruby?
Ruby Shoes (by why) is intended to be a really simple GUI framework. I don't know how fully featured it is, though.
Some good code samples can be found in the tutorials.
Also, I think shoes powers hackety hack, a compelling programming learning environment for youngsters.
Here is a good resource for you:
http://en.wikibooks.org/wiki/Ruby_Programming/GUI_Toolkit_Modules
has links comparing basically all of them.
I started with FXRuby because it had a book.