whitespaces in the path of windows filepath

path = r"C:\Users\mememe\Google Drive\Programs\Python\file.csv"

Closing the path in r"string" also solved this problem very well.

There is no problem with whitespaces in the path since you're not using the "shell" to open the file. Here is a session from the windows console to prove the point. You're doing something else wrong

Python 2.7.2 (default, Jun 12 2011, 14:24:46) [MSC v.1500 64 bit (AMD64)] on wi
32
Type "help", "copyright", "credits" or "license" for more information.
>>> import os
>>>
>>> os.makedirs("C:/ABC/SEM 2/testfiles")
>>> open("C:/ABC/SEM 2/testfiles/all.txt","w")
<open file 'C:/ABC/SEM 2/testfiles/all.txt', mode 'w' at 0x0000000001D95420>
>>> exit()

C:\Users\Gnibbler>dir "C:\ABC\SEM 2\testfiles"
 Volume in drive C has no label.
 Volume Serial Number is 46A0-BB64

 Directory of c:\ABC\SEM 2\testfiles

13/02/2013  10:20 PM    <DIR>          .
13/02/2013  10:20 PM    <DIR>          ..
13/02/2013  10:20 PM                 0 all.txt
               1 File(s)              0 bytes
               2 Dir(s)  78,929,309,696 bytes free

C:\Users\Gnibbler>

Try putting double quotes in your filepath variable

"\"E:/ABC/SEM 2/testfiles/all.txt\""

Check the permissions of the file or in any case consider renaming the folder to remove the space