Accessing a resource via codebehind in WPF

You should use System.Windows.Controls.UserControl's FindResource() or TryFindResource() methods.

Also, a good practice is to create a string constant which maps the name of your key in the resource dictionary (so that you can change it at only one place).

You may also use this.Resources["mykey"]. I guess that is not much better than your own suggestion.

Not exactly direct answer, but strongly related:

In case the resources are in a different file - for example ResourceDictionary.xaml

You can simply add x:Class to it:

<ResourceDictionary x:Class="Namespace.NewClassName"
                    xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
                    xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml" >
    <ds:MyCollection x:Key="myKey" x:Name="myName" />
</ResourceDictionary>

And then use it in code behind:

var res = new Namespace.NewClassName();
var col = res["myKey"];