Add primary key to PostgreSQL table only if it does not exist

You could do something like the following, however it is better to include it in the create table as a_horse_with_no_name suggests.

if NOT exists (select constraint_name from information_schema.table_constraints where table_name = 'table_name' and constraint_type = 'PRIMARY KEY') then

ALTER TABLE table_name
  ADD PRIMARY KEY (id);

end if;

You can try to DROP it before creating it (DROP has the IF EXISTS clause):

ALTER TABLE mail_app_recipients DROP CONSTRAINT IF EXISTS mail_app_recipients_pkey;
ALTER TABLE mail_app_recipients ADD CONSTRAINT mail_app_recipients_pkey PRIMARY KEY ("id_draft","id_person");

Note that this require that you give a name to the primary key constraint - in this example mail_app_recipients_pkey.

Why not include the PK definition inside the CREATE TABLE:

CREATE TABLE IF NOT EXISTS mail_app_recipients
(
    id_draft Integer NOT NULL,
    id_person Integer NOT NULL,
    constraint pk_mail_app_recipients primary key (id_draft, id_person)
)