CSS3 Spin Animation

You haven't specified any keyframes. I made it work here.

div {
    margin: 20px;
    width: 100px; 
    height: 100px;    
    background: #f00;
    -webkit-animation: spin 4s infinite linear;
}

@-webkit-keyframes spin {
    0%  {-webkit-transform: rotate(0deg);}
    100% {-webkit-transform: rotate(360deg);}   
}

You can actually do lots of really cool stuff with this. Here is one I made earlier.

:)

N.B. You can skip having to write out all the prefixes if you use -prefix-free.

To use CSS3 Animation you must also define the actual animation keyframes (which you named spin)

Read https://developer.mozilla.org/en-US/docs/CSS/Tutorials/Using_CSS_animations for more info

Once you've configured the animation's timing, you need to define the appearance of the animation. This is done by establishing two or more keyframes using the @keyframes at-rule. Each keyframe describes how the animated element should render at a given time during the animation sequence.

Demo :

div {
    margin: 20px;
    width: 100px;
    height: 100px;
    background: #f00;
    -webkit-animation-name: spin;
    -webkit-animation-duration: 4000ms;
    -webkit-animation-iteration-count: infinite;
    -webkit-animation-timing-function: linear;
    -moz-animation-name: spin;
    -moz-animation-duration: 4000ms;
    -moz-animation-iteration-count: infinite;
    -moz-animation-timing-function: linear;
    -ms-animation-name: spin;
    -ms-animation-duration: 4000ms;
    -ms-animation-iteration-count: infinite;
    -ms-animation-timing-function: linear;
    
    animation-name: spin;
    animation-duration: 4000ms;
    animation-iteration-count: infinite;
    animation-timing-function: linear;
}
@-ms-keyframes spin {
    from { -ms-transform: rotate(0deg); }
    to { -ms-transform: rotate(360deg); }
}
@-moz-keyframes spin {
    from { -moz-transform: rotate(0deg); }
    to { -moz-transform: rotate(360deg); }
}
@-webkit-keyframes spin {
    from { -webkit-transform: rotate(0deg); }
    to { -webkit-transform: rotate(360deg); }
}
@keyframes spin {
    from {
        transform:rotate(0deg);
    }
    to {
        transform:rotate(360deg);
    }
}

<div></div>

@-moz-keyframes spin {
    from { -moz-transform: rotate(0deg); }
    to { -moz-transform: rotate(360deg); }
}
@-webkit-keyframes spin {
    from { -webkit-transform: rotate(0deg); }
    to { -webkit-transform: rotate(360deg); }
}
@keyframes spin {
    from {transform:rotate(0deg);}
    to {transform:rotate(360deg);}
}