Does an MKV tag/metadata editor for Mac OSX exist?
The best tool you can get for this task is mmg
as part of the mkvtoolnix
package:
http://www.bunkus.org/videotools/mkvtoolnix/
It contains a header-editor where you can change the 'tags'. It is available cross-platform, the link you are most interested in should be http://www.bunkus.org/videotools/mkvtoolnix/downloads.html#macosx.