Expected number of loops
Suppose you start with $n$ ropes. You pick two free ends and tie them together:
If you happened to pick two ends of the same rope, you've added one additional loop (which you can set aside, since you'll never pick it now on), and have $n-1$ ropes
If you happened to pick ends of different ropes, you've added no loop, and effectively replaced the two ropes with a longer rope, so you have $n-1$ ropes in this case too.
Of the $\binom{2n}{2}$ ways of choosing two ends, $n$ of them result in the first case, so the first case has probability $\frac{n}{2n(2n-1)/2} = 1/(2n-1)$. So the expected number of loops you add in the first step, when you start with $n$ ropes, is $$\left(\frac{1}{2n-1}\right)1 + \left(1-\frac{1}{2n-1}\right)0 = \frac{1}{2n-1}.$$
After this, you start over with $n-1$ ropes. Since what happens in the first step and later are independent (and expectation is linear anyway), the expected number of loops is $$ \frac{1}{2n-1} + \frac{1}{2n-3} + \dots + \frac{1}{3} + 1 = H_{2n} - \frac{H_n}{2}$$
In particular, for $n=100$, the answer is roughly $3.28$, which come to think of it seems surprisingly small for the number of loops!