Get contents of laccdb file through VBA
I found this which should help, it's not actually reading the ldb file, but it has the info that you need (Source: https://support.microsoft.com/en-us/kb/198755):
Sub ShowUserRosterMultipleUsers()
Dim cn As New ADODB.Connection
Dim cn2 As New ADODB.Connection
Dim rs As New ADODB.Recordset
Dim i, j As Long
cn.Provider = "Microsoft.Jet.OLEDB.4.0"
cn.Open "Data Source=c:\Northwind.mdb"
cn2.Open "Provider=Microsoft.Jet.OLEDB.4.0;" _
& "Data Source=c:\Northwind.mdb"
' The user roster is exposed as a provider-specific schema rowset
' in the Jet 4 OLE DB provider. You have to use a GUID to
' reference the schema, as provider-specific schemas are not
' listed in ADO's type library for schema rowsets
Set rs = cn.OpenSchema(adSchemaProviderSpecific, _
, "{947bb102-5d43-11d1-bdbf-00c04fb92675}")
'Output the list of all users in the current database.
Debug.Print rs.Fields(0).Name, "", rs.Fields(1).Name, _
"", rs.Fields(2).Name, rs.Fields(3).Name
While Not rs.EOF
Debug.Print rs.Fields(0), rs.Fields(1), _
rs.Fields(2), rs.Fields(3)
rs.MoveNext
Wend
End Sub