How to get an arbitrary element from a frozenset?

If you know that there is but one element in the frozenset, you can use iterable unpacking:

s = frozenset(['a'])
x, = s

This is somewhat a special case of the original question, but it comes in handy some times.

If you have a lot of these to do it might be faster than next(iter..:

>>> timeit.timeit('a,b = foo', setup='foo = frozenset(range(2))', number=100000000)
5.054765939712524
>>> timeit.timeit('a = next(iter(foo))', setup='foo = frozenset(range(2))', number=100000000)
11.258678197860718

(Summarizing the answers given in the comments)

Your method is as good as any, with the caveat that, from Python 2.6, you should be using next(iter(s)) rather than iter(s).next().

If you want a random element rather than an arbitrary one, use the following:

import random
random.sample(s, 1)[0]

Here are a couple of examples demonstrating the difference between those two:

>>> s = frozenset("kapow")
>>> [next(iter(s)) for _ in range(10)]
['a', 'a', 'a', 'a', 'a', 'a', 'a', 'a', 'a', 'a']

>>> import random
>>> [random.sample(s, 1)[0] for _ in range(10)]
['w', 'a', 'o', 'o', 'w', 'o', 'k', 'k', 'p', 'k']