Eigenvalues of symmetric orthogonal matrix

Yes, you're right. Also note that if $A^\top A=I$ and $A=A^\top$, then $A^2=I$, and now it's immediate that $\pm 1$ are the only possible eigenvalues. (Indeed, applying the spectral theorem, you can now conclude that any such $A$ can only be an orthogonal reflection across some subspace.)