Proof of this inequality

Your conjecture fails for $n \ge 7$ (and maybe for some smaller $n$). The following results are from programming your inequality in Sage and testing a variety of patterned sequences.

1. First family of counterexamples

Let $S(a,b) = [a, a-1, a-2, ..., 1, b, b-1, b-2,..., 1]$, of length $a+b$, for positive integers $a,b$.

For any $a \ge 2$, there is some $b^* \gt a$ such that for any $b \ge b^*$, $S(a, b)$ is a counterexample. (The quantity $\ \text{LHS}-\text{RHS}\ $ is a decreasing function of $b$, and falls below $0$ at $b=b^*$.)

Such counterexamples include $S(2, b\ge 11), S(3, b\ge 14), S(4, b\ge 16), S(5,b\ge 19)$, and so on. (I haven't determined a formula for $b^*$.)

The smallest counterexample of this form appears to be $$S(2,11) = [2, 1, 11, 10, 9, 8, 7, 6, 5, 4, 3, 2, 1]$$ for which
$$\text{LHS} = \frac{79582008868974649241}{15735265132809166560} = 5.0575... < 5.0608... = \frac{1185342437701}{234217526928} = \text{RHS} $$

2. Second (shorter) family of counterexamples

Another family of counterexamples is $[2, b, b, b, b, b, 1]$ with $b \ge 5$. The smallest counterexample of this form appears to be $[2, 5, 5, 5, 5, 5, 1]$, for which
$$\text{LHS} = \frac{3515219}{1225224} = 2.869... < 2.881... = \frac{30446902}{10567557} = \text{RHS} $$

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Here's the core of the program (note the indexing adjustments due to Python lists being $0$-based):

def lhs(L,j):
    n = len(L)
    tot = (L[0] + L[n-1])/sum(L)
    for i in [j+1..n-2]: tot += L[i]^2 / ( sum(L[0:i+1])*( L[n-1] + sum(L[1:i+1]) ) )
    return (L[n-1] + sum(L[1:j+1]))*tot

def rhs(L,j):
    n = len(L)
    tot = L[n-1]/sum(L)
    for i in [j+1..n-2]: tot += L[i]^2 / ( sum(L[0:i+1])*( L[n-1] + sum(L[0:i+1]) ) )
    return (L[n-1] + sum(L[0:j+1]))*tot 

for b in [3..8]:
    L = [2,b,b,b,b,b,1]; left = lhs(L,1); right = rhs(L,1)
    print b, left.n(), right.n(), (left-right).n()

> 3 1.96695167577521 1.92603768780239 0.0409139879728115
> 4 2.41522132314971 2.40469223123685 0.0105290919128582
> 5 2.86904190580661 2.88116752055371 -0.0121256147470981
> 6 3.32586148147269 3.35536963036963 -0.0295081488969435
> 7 3.78448484495198 3.82769776396051 -0.0432129190085339
> 8 4.24427752155089 4.29855086580553 -0.0542733442546420