Proving the inequality $4\ge a^2b+b^2c+c^2a+abc$
So we need to show $$4(a+b+c)^3 \ge 27(a^2b+b^2c+c^2a+abc)$$
One way is to use the cyclic symmetry and WLOG assume $a$ to be the min of $a, b, c$. Then we can write $b = a+x, c = a+y$, where $x, y \ge 0$. Now the inequality reduces to $$9a(x^2-xy+y^2)+(x-2y)^2(4x+y) \ge 0$$ which is obvious. Also from the above, we get that equality is possible iff $x=y=0$ or when $a=0, x=2y$, i.e. when $(a, b, c)=(1, 1, 1)$ or is a permutation of $(0, 2, 1)$.
Let $\{a,b,c\}=\{x,y,z\}$, where $x\geq y\geq z$.
Hence, by Rearrangement and AM-GM we obtain:
$a^2b+b^2c+c^2a+abc=a\cdot ab+b\cdot bc+c\cdot ca+abc\leq x\cdot xy+y\cdot xz+z\cdot yz+xyz=$
$=y(x+z)^2=4y\left(\frac{x+z}{2}\right)^2\leq4\left(\frac{y+\frac{x+z}{2}+\frac{x+z}{2}}{3}\right)^3=4$.