Serialize Class containing Dictionary member

You can't serialize a class that implements IDictionary. Check out this link.

Q: Why can't I serialize hashtables?

A: The XmlSerializer cannot process classes implementing the IDictionary interface. This was partly due to schedule constraints and partly due to the fact that a hashtable does not have a counterpart in the XSD type system. The only solution is to implement a custom hashtable that does not implement the IDictionary interface.

So I think you need to create your own version of the Dictionary for this. Check this other question.

There is a solution at Paul Welter's Weblog - XML Serializable Generic Dictionary

For some reason, the generic Dictionary in .net 2.0 is not XML serializable. The following code snippet is a xml serializable generic dictionary. The dictionary is serialzable by implementing the IXmlSerializable interface.

using System;
using System.Collections.Generic;
using System.Text;
using System.Xml.Serialization;

[XmlRoot("dictionary")]
public class SerializableDictionary<TKey, TValue>
    : Dictionary<TKey, TValue>, IXmlSerializable
{
    public SerializableDictionary() { }
    public SerializableDictionary(IDictionary<TKey, TValue> dictionary) : base(dictionary) { }
    public SerializableDictionary(IDictionary<TKey, TValue> dictionary, IEqualityComparer<TKey> comparer) : base(dictionary, comparer) { }
    public SerializableDictionary(IEqualityComparer<TKey> comparer) : base(comparer) { }
    public SerializableDictionary(int capacity) : base(capacity) { }
    public SerializableDictionary(int capacity, IEqualityComparer<TKey> comparer) : base(capacity, comparer) { }

    #region IXmlSerializable Members
    public System.Xml.Schema.XmlSchema GetSchema()
    {
        return null;
    }

    public void ReadXml(System.Xml.XmlReader reader)
    {
        XmlSerializer keySerializer = new XmlSerializer(typeof(TKey));
        XmlSerializer valueSerializer = new XmlSerializer(typeof(TValue));

        bool wasEmpty = reader.IsEmptyElement;
        reader.Read();

        if (wasEmpty)
            return;

        while (reader.NodeType != System.Xml.XmlNodeType.EndElement)
        {
            reader.ReadStartElement("item");

            reader.ReadStartElement("key");
            TKey key = (TKey)keySerializer.Deserialize(reader);
            reader.ReadEndElement();

            reader.ReadStartElement("value");
            TValue value = (TValue)valueSerializer.Deserialize(reader);
            reader.ReadEndElement();

            this.Add(key, value);

            reader.ReadEndElement();
            reader.MoveToContent();
        }
        reader.ReadEndElement();
    }

    public void WriteXml(System.Xml.XmlWriter writer)
    {
        XmlSerializer keySerializer = new XmlSerializer(typeof(TKey));
        XmlSerializer valueSerializer = new XmlSerializer(typeof(TValue));

        foreach (TKey key in this.Keys)
        {
            writer.WriteStartElement("item");

            writer.WriteStartElement("key");
            keySerializer.Serialize(writer, key);
            writer.WriteEndElement();

            writer.WriteStartElement("value");
            TValue value = this[key];
            valueSerializer.Serialize(writer, value);
            writer.WriteEndElement();

            writer.WriteEndElement();
        }
    }
    #endregion
}