Using media breakpoints in Bootstrap 4-alpha

Update: Bootstrap 5.

v5 breakpoints reference

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Original answer - Bootstrap v4: Use breakpoint mixins like this:

.something {
    padding: 5px;
    @include media-breakpoint-up(sm) { 
        padding: 20px;
    }
    @include media-breakpoint-up(md) { 
        padding: 40px;
    }
}

v4 breakpoints reference

v4 alpha6 breakpoints reference

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Below full options and values.

Breakpoint & up (toggle on value and above):

@include media-breakpoint-up(xs) { ... }
@include media-breakpoint-up(sm) { ... }
@include media-breakpoint-up(md) { ... }
@include media-breakpoint-up(lg) { ... }
@include media-breakpoint-up(xl) { ... }

breakpoint & up values:

// Extra small devices (portrait phones, less than 576px)
// No media query since this is the default in Bootstrap

// Small devices (landscape phones, 576px and up)
@media (min-width: 576px) { ... }

// Medium devices (tablets, 768px and up)
@media (min-width: 768px) { ... }

// Large devices (desktops, 992px and up)
@media (min-width: 992px) { ... }

// Extra large devices (large desktops, 1200px and up)
@media (min-width: 1200px) { ... }

breakpoint & down (toggle on value and down):

@include media-breakpoint-down(xs) { ... }
@include media-breakpoint-down(sm) { ... }
@include media-breakpoint-down(md) { ... }
@include media-breakpoint-down(lg) { ... }

breakpoint & down values:

// Extra small devices (portrait phones, less than 576px)
@media (max-width: 575px) { ... }

// Small devices (landscape phones, less than 768px)
@media (max-width: 767px) { ... }

// Medium devices (tablets, less than 992px)
@media (max-width: 991px) { ... }

// Large devices (desktops, less than 1200px)
@media (max-width: 1199px) { ... }

// Extra large devices (large desktops)
// No media query since the extra-large breakpoint has no upper bound on its width

breakpoint only:

@include media-breakpoint-only(xs) { ... }
@include media-breakpoint-only(sm) { ... }
@include media-breakpoint-only(md) { ... }
@include media-breakpoint-only(lg) { ... }
@include media-breakpoint-only(xl) { ... }

breakpoint only values (toggle in between values only):

// Extra small devices (portrait phones, less than 576px)
@media (max-width: 575px) { ... }

// Small devices (landscape phones, 576px and up)
@media (min-width: 576px) and (max-width: 767px) { ... }

// Medium devices (tablets, 768px and up)
@media (min-width: 768px) and (max-width: 991px) { ... }

// Large devices (desktops, 992px and up)
@media (min-width: 992px) and (max-width: 1199px) { ... }

// Extra large devices (large desktops, 1200px and up)
@media (min-width: 1200px) { ... }

I answered a similar question here

As @Syden said, the mixins will work. Another option is using SASS map-get like this..

@media (min-width: map-get($grid-breakpoints, sm)){
  .something {
    padding: 10px;
   }
}

@media (min-width: map-get($grid-breakpoints, md)){
  .something {
    padding: 20px;
   }
}

http://www.codeply.com/go/0TU586QNlV

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Bootstrap 4 Breakpoints demo