What's the highest theoretical energy density for a chemical battery?

I don't know the actual answer to this question, but I know a least upper bound to the answer, and a means of figuring out the real answer.

Battery scientists have a metric called maximum theoretical specific energy; you can read about the definition in Advanced Batteries by Robert Huggins. Right now, the most energy dense batteries you can buy are lithium ion, which are in the 100-200 Wh/kg range. I don't know what the best battery is, but later in the book, Huggins shows calculations that indicate that Li/CuCl2 cells have an MTSE of 1166.4 Wh/kg. (5x the capacity of current batteries!)

We know that the highest MTSE is at least 1166.4 Wh/kg; you could use his method to calculate the same value for other chemistries, but the search space is pretty large.

I've also seen references on the internet to Li/O2 and Al/O2 batteries with MTSE of 2815 and 5200 Wh/kg, respectively. Not sure how credible those references are. Later references, like this 2008 article in the Journal of the Electrochemical Society, suggest that the MTSE for a Li/O2 cell is around 1400 Wh/kg.


If we want to broaden "battery" to mean some sort of device that generates electricity based on a chemical reaction (via magical means), the upper 100% efficient limit would be the chemical enthalpy of the reaction.

Calculations for a theoretical "sugar+air" battery:

  • Standard enthalpy of combustion of glucose: −2805 kJ/mol (I think this is a shortcut beyond decomposition into standard elements?)
  • 2805 kJ/mol / 180 g/mol = 4328 W·h/kg

Not sure what the most chemically dense compound is, but you could just plug it into that.

Nuclear powered cells could be even more magical, E=mc²:

  • 1 kg × c² = 2.5 × 10**13 W·h

Current state of the art lithium/sulfur batteries are about 350 Wh/kg. And therefore not unobtainium like many of the listed chemistries.

Here's some detailed info: https://en.wikipedia.org/wiki/Lithium-sulfur_battery