Apple - "You don't have permission to save files in the location where screen shots are stored"
If you type defaults read com.apple.screencapture location
into a Terminal window it should tell you where OSX is currently trying to save screenshots.
You can change the location with a similar command. For example:
defaults write com.apple.screencapture location ~/Desktop
will save screenshots to your Desktop.
defaults write com.apple.screencapture location ~/Documents
will save screenshots to your Documents folder.
Once you've told it a new location you need to run the following command for OSX to pick up the change.
killall SystemUIServer