WPF Binding - Notify Change to ToString value
I assume when you say the control is "binding" to ToString() that your object is being used as Content on ContentControl somewhere inside the inaccessible code which by default creates a TextBlock that displays the ToString value (if you're not sure you can find out with Snoop). If you create a global typed DataTemplate for your Person type in the control's Resources you can use that to display a different property, like a new FullName property:
<ThirdPartyControl.Resources>
<DataTemplate DataType="{x:Type data:Person}">
<TextBlock Text="{Binding FullName}"/>
</DataTemplate>
</ThirdPartyControl.Resources>
If you don't want to add a specialized property for the full name, you should be able to use StringFormat in you binding. See the MultiBinding example in this blog post. [Requires .NET 3.5 SP1]