Why is <deny users="?" /> included in the following example?
"At run time, the authorization module iterates through the allow and deny elements, starting at the most local configuration file, until the authorization module finds the first access rule that fits a particular user account. Then, the authorization module grants or denies access to a URL resource depending on whether the first access rule found is an allow or a deny rule. The default authorization rule is . Thus, by default, access is allowed unless configured otherwise."
Article at MSDN
deny = * means deny everyone
deny = ? means deny unauthenticated users
In your 1st example deny * will not affect dan, matthew since they were already allowed by the preceding rule.
According to the docs, here is no difference in your 2 rule sets.
ASP.NET grants access from the configuration file as a matter of precedence. In case of a potential conflict, the first occurring grant takes precedence. So,
deny user="?"
denies access to the anonymous user. Then
allow users="dan,matthew"
grants access to that user. Finally, it denies access to everyone. This shakes out as everyone except dan,matthew is denied access.
Edited to add: and as @Deviant points out, denying access to unauthenticated is pointless, since the last entry includes unauthenticated as well. A good blog entry discussing this topic can be found at: Guru Sarkar's Blog